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Superstructures

Los Alamos National Laboratory researchers have synthesized well-defined hybrid noble-metal/SiO2/semiconductor-nanocrystal superstructures with controllable metal core size, silica shell thickness, and nanocrystal composition/size. These structures can be designed to produce significant enhancements in emission efficiencies and/or absorption cross sections compared to isolated nanocrystals.

Applications

  • Ultra thin (potentially single nanoparticle layer) solar cells dual fluorescence/Raman sensing and imaging
  • Solid-state lighting
  • Amplification of surface plasmons

Advantages

  • Simplicity of the synthetic route
  • Possibility for tuning emission and absorption spectra using the same chemistry
  • Precise control of interactions of light emitting/absorbing chromophores with a metal provided by continuous management of the silica spacer width
  • Possibility for obtaining increased emission efficiencies
  • Significant enhancement in absorption cross sections.

More info: David Pesiri, 505-665-7279, pesiri@lanl.gov